Rosliana Rusli and Salasiah Endud and Hendrik O. Lintang and Zainab Ramli (2016) 12.1. Hendrik - ARTIKEL: Synthesis of Tetra. Malaysian Journal of Chemistry, 18 (2). pp. 82-89. ISSN e-ISSN: 2550-1658
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Archive (ARTIKEL: Synthesis of Tetra(m-nitrophenyl) porphyrin)
12.1._Hendrik_ARTIKEL_synthesis_of_tetra.pdf - Published Version Download (2MB) | Preview |
Abstract
The monitoring of lead in the environment has gained importance because lead(II) ion is a toxic metal ion causing adverse environmental and health problems. In this paper, we reported the synthesis of 5,10,15,20-tetra(m-nitrophenyl)porphyrin as a sensing material aimed at the recognition of lead(II) ion. The synthesis and ion binding characteristics of the 5,10,15,20-tetra(m-nitrophenyl)porphyrin were investigated using FTIR, 1H NMR, and UV-Vis spectroscopy. The binding of lead(II) ion to the 5,10,15, 20-tetra(mnitrophenyl)porphyrin was found to give a new peak in the absorption spectra at 473.35 nm along with two isosbestic points at 483 nm and 465 nm, suggesting porphyrin complex formation of 5,10,15, 20-tetra(m-nitrophenyl)porphyrin-lead(II). The calculated limit of detection for lead(II) ion using 5,10,15, 20-tetra(m-nitrophenyl)porphyrin is 3.67 X 10–4 M and the association constant, Kass is 1.56 X 102 M–1. Herein, it was proposed that a new coordination compound was formed between lead(II) ion with 5,10,15, 20-tetra(mnitrophenyl)porphyrin through nitro group chromophore.
| Item Type: | Article |
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| Subjects: | Q Science > QD Chemistry |
| Depositing User: | Administrator Ma Chung |
| Date Deposited: | 14 Nov 2017 16:35 |
| Last Modified: | 14 Nov 2017 16:35 |
| URI: | http://eprints.machung.ac.id//id/eprint/59 |
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